Hysteretic magnetism–dielectricity switching in 2D Hofmann type spin-crossover compounds
Nian‐Tao Yao, Meng‐Jia Shang, Han‐Han Lu, Qiang Liu, Wen Wen, Shihui Zhang, Liang Zhao, Hiroki Oshio, Yin‐Shan Meng, Tao Liu
Abstract
Two 2D Hofmann type compounds {Fe(3,4-bpt) 2 [M(CN) 4 ]} were synthesized. They showed reversible switching in magnetism, dielectricity, and thermochromism actuated by the spin transition of Fe( ii ).
Topics & Concepts
MagnetismThermochromismSpin crossoverCondensed matter physicsSpin (aerodynamics)ChemistryType (biology)Materials scienceCrystallographyPhysicsThermodynamicsBiologyEcologyMagnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryOrganic and Molecular Conductors Research