The enthalpic and entropic terms of the reduction potential of metalloproteins: Determinants and interplay
Giulia Di Rocco, Gianantonio Battistuzzi, Marco Borsari, Carlo Augusto Bortolotti, Antonio Ranieri, Marcó Sola
Topics & Concepts
ChemistryEnthalpyEntropy (arrow of time)RedoxElectron transport chainChemical physicsMetalloproteinMetalRubredoxinThermodynamicsSelenocysteineHemeComputational chemistryCrystallographyInorganic chemistryCysteineOrganic chemistryEnzymeBiochemistryPhysicsPhotosynthetic Processes and MechanismsMetal-Catalyzed Oxygenation MechanismsMetalloenzymes and iron-sulfur proteins