Key intermediates from simultaneous removal of NO<sub><i>x</i></sub> and chlorobenzene over a V<sub>2</sub>O<sub>5</sub>–WO<sub>3</sub>/TiO<sub>2</sub> catalyst: a combined experimental and DFT study
Chuan Gao, Guangpeng Yang, Xu Huang, Qilei Yang, Bing Li, Dong Wang, Yue Peng, Junhua Li, Chunmei Lu, John C. Crittenden
Abstract
Chlorobenzene suppresses the active cis -N 2 O 2 2− formation and the dissociated Cl − combines with vanadium to form vanadium chloride which enhanced surface Brønsted acidity.
Topics & Concepts
ChlorobenzeneVanadiumCatalysisChlorideReaction intermediateInorganic chemistryChemistryMaterials sciencePhysicsOrganic chemistryCatalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsIndustrial Gas Emission Control