Synthesis and isolation of a cyclic bis-vinyl germylene <i>via</i> a diazoolefin adduct of germylene dichloride
Teresa Eisner, Arseni Kostenko, Fiona J. Kiefer, Shigeyoshi Inoue
Abstract
Since the successful isolation of various stable diazoolefins, an array of complexes containing these promising ligands have been synthesized. We herein report the synthesis, characterization, and structures of neutral group 14 diazoolefin complexes and the subsequent transformation into a new cyclic bis-vinyl germylene.
Topics & Concepts
AdductChemistryGermaniumDerivative (finance)Germanium compoundsOrganic chemistryPolymer chemistrySiliconEconomicsFinancial economicsSynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and CatalysisCoordination Chemistry and Organometallics