Visible-light-induced phosgenation of amines by chloroform oxygenation using chlorine dioxide
Haruyasu Asahara, Nozomi Takao, Maiko Moriguchi, Tsuyoshi Inoue, Kei Ohkubo
Abstract
through the oxygenation of chloroform in the presence of chlorine dioxide, which leads to the safe constructions of carbamoyl chlorides with good-to-high yields and wide substrate scopes. In addition, this method can also be applied to the synthesis of various carbonates.
Topics & Concepts
ChloroformChlorine dioxideOxygenationChemistryChlorineOxygenPhotochemistryInorganic chemistryChromatographyOrganic chemistryAnesthesiaMedicineSynthesis and Catalytic ReactionsRadical Photochemical ReactionsChemical Synthesis and Reactions