Peroxomolybdate@MOFs as effective catalysts for oxidative desulfurization of fuels: correlation between MOF structure and catalytic activity
Yan Gao, Carlos M. Granadeiro, Luı́s Cunha-Silva, Jianshe Zhao, Salete S. Balula
Abstract
The highly active peroxomolybdate, TBA 3 {PO 4 [MoO(O 2 ) 2 ] 4 }·3H 2 O was incorporated for the first time in various porous MOF support structures (MIL-101, MOF-808, and ZIF-8) to form heterogeneous catalysts with different structural properties.
Topics & Concepts
CatalysisFlue-gas desulfurizationPorosityOxidative phosphorylationChemistryChemical engineeringMaterials scienceOrganic chemistryBiochemistryEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsCatalysis and Hydrodesulfurization StudiesPolyoxometalates: Synthesis and Applications