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Diffusion and Dissolution Behaviors of CO<sub>2</sub>, CH<sub>4</sub>, and N<sub>2</sub> in Heavy Oil under High-Temperature and -Pressure Conditions: Insights into Heavy Oil Production via Multithermal Fluid Stimulation

Hanxing Su, Haitao Wang, Dongyang Li, Dengfeng Zhang

2023Energy & Fuels11 citationsDOI

Abstract

To comprehend heavy oil production well via the multithermal fluid stimulation technology, the diffusion and dissolution processes of CO 2, CH 4, and N 2 in heavy oil were conducted under a temperature range of 308.15–423.15 K and bulk pressures up to 20 MPa. Accordingly, the diffusion coefficients and solubilities of CO 2, CH 4, and N 2 were measured. Results indicated that the diffusion coefficients of CO 2, CH 4, and N 2 in heavy oil increase with rising temperature and decrease with rising pressure. The diffusion capability of these fluids in heavy oil conforms to the order CH 4 > CO 2 > N 2 . Moreover, the solubility of CO 2, CH 4, and N 2 in heavy oil is negatively related to temperature and positively related to pressure. The solubility of various fluids in heavy oil decreases in the sequence of CO 2 > CH 4 > N 2 . The diffusion and dissolution of CO 2, CH 4, and N 2 could induce volume expansion, colloidal structure damage, intermolecular force alteration, gap filling, and light component extraction toward heavy oil, thereby promoting its quality and recovery. Overall, heavy oil production via the multithermal fluid stimulation technology is recommended to be implemented under high-temperature and -pressure conditions.

Topics & Concepts

DissolutionSolubilityDiffusionChemistryVolume (thermodynamics)AsphalteneMaterials scienceThermodynamicsOrganic chemistryPhysicsHydrocarbon exploration and reservoir analysisPetroleum Processing and AnalysisEnhanced Oil Recovery Techniques