Comparison study between as-synthesized ZnO and ZnO derived from ZiF-8 metalorganic framework in removing methylene blue
Abdelaziz M. Aboraia, Abdullah Almohammedi, Shoroog Alraddadi, Safeya A. Taha, Mohamed Saad, Ibrahim M. Sharaf, Yasser A. M. Ismail
Abstract
The nanoporous materials derived from the ZiF-8 metalorganic framework are highly interesting because of their features like good thermal stability, catalytic performance, and electric conductivity. Therefore, ZiF-derived metal oxide was utilized in several applications, for instance, energy storage and environmental remediations. Herin, we compare the as-prepared ZnO, ZiF-8, and ZnO derived from ZiF-8 in terms of structural, thermal, and morphological properties. Thus, the photocatalytic performance of all compositions. The preparation process is an effective parameter in the morphology of the sample surface. The as-synthesized ZnO had nanoparticle morphology with a size of 50–80[Formula: see text]nm. However, the ZiF-8 has cubic morphology with a long rod. The decomposition of ZiF-8 converted the sample to ZnO coated by carbon, indicating a high surface and fit morphology for photocatalysis. These results mean that ZnO derivative from ZiF-8 nanoparticles has the best efficiency for water desalination with 95%. ZnO drives from ZiF-8 demonstrated the smallest charge transfer resistance compared to that of as-prepared ZnO, and ZIF-8, coinciding with the conclusion of the EIS results. The transient photoresponses and electrochemical impedance spectra of the compounds were used further to explore the separation efficiency of the photogenerated charge carriers.