The effect of ancillary ligands on hydrocarbon C–H bond functionalization by uranyl photocatalysts
Ryte Rutkauskaite, Xiaobin Zhang, Adam W. Woodward, Yanlin Liu, Gabriel Herrera-Rodríguez, Jamie M. Purkis, Sean D. Woodall, Mark J. Sarsfield, Georg Schreckenbach, Louise S. Natrajan, Polly L. Arnold
Abstract
phen ligand provide control over the H atom abstraction, and provide predictions of selectivity of H atom abstraction by the uranyl oxo of the ring C-H over the ethyl C-H in an ethylcyclohexane substrate.
Topics & Concepts
Surface modificationUranylCatalysisChemistryHydrocarbonPhotochemistryCombinatorial chemistryOrganic chemistryPhysical chemistryIonRadioactive element chemistry and processingCO2 Reduction Techniques and CatalystsElectrochemical Analysis and Applications