Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal–organic frameworks
Shiyu Zhang, Dillip K. Panda, Ashok Yadav, Wei Zhou, Sourav Saha
Abstract
IVCT interaction on their electronic and optical properties, demonstrating that IVCT interactions between the mixed-valent ligands could be exploited as an effective design strategy to develop electrically conducting MOFs.
Topics & Concepts
TetrathiafulvaleneMetal-organic frameworkCharge (physics)Materials scienceMetalElectrical resistivity and conductivityConductivityCharge-transfer complexChemistryNanotechnologyPhotochemistryOrganic chemistryPhysical chemistryMoleculeElectrical engineeringPhysicsMetallurgyQuantum mechanicsEngineeringAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsOrganic and Molecular Conductors ResearchMagnetism in coordination complexes