Photocatalytic three-component radical cascade: a general route to heterocyclic-substituted alkyl sulfones
Jian‐Qiang Chen, Nana Liu, Qian Hu, Jin Liu, Junwei Wu, Junwei Wu, Qinling Cai, Jie Wu, Jie Wu
Abstract
A photoredox-catalyzed three-component radical cascade reaction of β,γ-unsaturated oximes/hydrazones, the sulfur dioxide surrogate of DABCO·(SO 2 ) 2 and alkenes under mild conditions is developed.
Topics & Concepts
ChemistryDABCOAlkylCascadePhotocatalysisSulfurPhotoredox catalysisOrganic chemistryComponent (thermodynamics)Sulfur dioxideCatalysisPhotochemistryThermodynamicsPhysicsChromatographySulfur-Based Synthesis TechniquesRadical Photochemical ReactionsChemical Synthesis and Reactions