Pretreatment to Retrieve Xylose and Xylooligosaccharides by HCl Gas Directly from Biomass
A. Topias Kilpinen, Kaarlo Nieminen, Eero Kontturi
Abstract
In this study, anhydrous hydrogen chloride gas was employed to selectively hydrolyze hemicellulose from aspen wood flour utilizing a gas-solid system. Selectivity toward hemicellulose was achieved by adjusting the acid concentration inside wood flour to 36% during gas hydrolysis, so only hemicellulose and disordered cellulose would be degraded during hydrolysis. Process parameters included the moisture content of the aspen wood flour (20%, 40%, and 60%) and reaction times from 30 min to 24 h. The optimal reaction conditions for the production of xylose and xylooligosaccharides was achieved with 40% moisture content and 6 h reaction time. Under these parameters, it was possible to retrieve 84% of the available xylan from aspen wood flour with only 1% glucan degradation.