Atomically precise surface chemistry of zirconium and hafnium metal oxo clusters beyond carboxylate ligands
Ajmal Roshan Unniram Parambil, Rohan Pokratath, Muhammed Jibin Parammal, Evert Dhaene, Dietger Van den Eynden, Sandor Balog, Alessandro Prescimone, Ivan Infante, Patrick Shahgaldian, Jonathan De Roo
Abstract
clusters and the challenge in preparing Zr phosphonate metal-organic frameworks. We thus further reinforce the notion that monoalkylphosphinates are carboxylate mimics with superior binding affinity.
Topics & Concepts
HafniumZirconiumCarboxylateChemistryMetalInorganic chemistryStereochemistryOrganic chemistryCatalytic Processes in Materials ScienceMachine Learning in Materials ScienceNanocluster Synthesis and Applications