Cycl[2,2,4]azine-embedded non-alternant nanographenes containing fused antiaromatic azepine ring
Lan Ruan, Wanhua Luo, H. Zhang, Peng Liu, Yong Shi, Peng An
Abstract
with a high association constant. Furthermore, selective modification of NG 1 was accomplished by Vilsmeier reaction, and the derivatives 7 and 8 with substituted benzophenone were obtained. The photophysical and electronic properties can be tuned by the introduction of different electronic groups in benzophenone.
Topics & Concepts
AntiaromaticityAzineAzepineChemistryRing (chemistry)AromaticityStereochemistryMedicinal chemistryOrganic chemistryMoleculeSynthesis and Properties of Aromatic CompoundsCovalent Organic Framework ApplicationsLuminescence and Fluorescent Materials