Litcius/Paper detail

Inside Back Cover: Efficient Splitting of Alkane Isomers by a Bismuth‐Based Metal‐Organic Framework with Auxetic Reentrant Pore Structures (Angew. Chem. Int. Ed. 47/2022)

Zhaoqiang Zhang, Shing Bo Peh, Chengjun Kang, Kexin Yu, Dan Zhao

2022Angewandte Chemie International Edition24 citationsDOIOpen Access PDF

Abstract

The energy-efficient separation of alkane isomers for gasoline upgrading using Bi-based metal-organic frameworks with auxetic reentrant pore structures is reported by Dan Zhao et al. in their Communication (e202211808). The honeycomb-like pore cavities connected by narrow pore windows of the pore structure lead to a complete rejection of di-branched alkanes and to high capacities for other isomers.

Topics & Concepts

AuxeticsAlkaneMaterials scienceMetal-organic frameworkReentrancyHoneycombBismuthNanotechnologyChemical engineeringHydrocarbonComposite materialChemistryPhysical chemistryOrganic chemistryCondensed matter physicsPhysicsEngineeringMetallurgyAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsMesoporous Materials and Catalysis