Redox Metal–Ligand Cooperativity Enables Robust and Efficient Water Oxidation Catalysis at Neutral pH with Macrocyclic Copper Complexes
Pablo Garrido‐Barros, Dooshaye Moonshiram, Marcos Gil‐Sepulcre, Primavera Pelosin, Carolina Gimbert‐Suriñach, Jordi Benet‐Buchholz, Antoni Llobet
Abstract
prevents its use at neutral pH due to acidic demetalation, highlighting the importance of the macrocyclic stabilization.
Topics & Concepts
ChemistryDelocalized electronLigand (biochemistry)CooperativityNon-innocent ligandCatalysisRedoxCatalytic oxidationMacrocyclic ligandOverpotentialPhotochemistryMetalCombinatorial chemistryInorganic chemistryElectrochemistryOrganic chemistryPhysical chemistryElectrodeBiochemistryReceptorElectrocatalysts for Energy ConversionMetal-Catalyzed Oxygenation MechanismsAdvanced battery technologies research