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Synthetic K<sup>+</sup>Channels Constructed by Rebuilding the Core Modules of Natural K<sup>+</sup>Channels in an Artificial System

Pengyang Xin, Linqi Xu, Wenpei Dong, Linlin Mao, Jingjing Guo, Jingjing Bi, Shouwei Zhang, Yan Pei, Changpo Chen

2022Angewandte Chemie International Edition34 citationsDOI

Abstract

Abstract Different types of natural K + channels share similar core modules and cation permeability characteristics. In this study, we have developed novel artificial K + channels by rebuilding the core modules of natural K + channels in artificial systems. All the channels displayed high selectivity for K + over Na + and exhibited a selectivity sequence of K + ≈Rb + during the transport process, which is highly consistent with the cation permeability characteristics of natural K + channels. More importantly, these artificial channels could be efficiently inserted into cell membranes and mediate the transmembrane transport of K + , disrupting the cellular K + homeostasis and eventually triggering the apoptosis of cells. These findings demonstrate that, by rebuilding the core modules of natural K + channels in artificial systems, the structures, transport behaviors, and physiological functions of natural K + channels can be mimicked in synthetic channels.

Topics & Concepts

Cell permeabilityChemistryPermeability (electromagnetism)MembraneSelectivityBiophysicsBiologyBiochemistryCatalysisIon channel regulation and functionMolecular Sensors and Ion DetectionSupramolecular Chemistry and Complexes