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Biosynthetic characterization of the antifungal fernane-type triterpenoid polytolypin for generation of new analogues <i>via</i> combinatorial biosynthesis

Xinyu Li, Jian‐Ming Lv, Zhiqin Cao, Gao‐Qian Wang, Fu-Long Lin, Guo‐Dong Chen, Sheng-Ying Qin, Dan Hu, Hao Gao, Xin‐Sheng Yao

2022Organic & Biomolecular Chemistry19 citationsDOI

Abstract

Characterization of polytolypin biosynthesis and generation of new polytolypin analogues via combinational expression of three new fernane cyclases with tailoring enzymes.

Topics & Concepts

ChemistryAntifungalBiosynthesisTriterpenoidTerpeneStereochemistryCombinatorial chemistryBiochemistryMicrobiologyGeneBiologyNatural product bioactivities and synthesisPlant biochemistry and biosynthesisPhytochemical compounds biological activities