Study on the adsorption mechanism of ciprofloxacin in wastewater by modified fly ash under the coexistence of copper
Jingbo Wang, Xinyue Li, Yushan Lan, Hanyu Wang, Hanyu Wang, Xiulan Ma, Hongbin Wang, Hongbin Wang, Haoyu Xu, Huiqing Liu
Abstract
The recontamination of farming wastewater with antibiotics and metal ions has emerged as a considerable concern in recent years. In this study, fly ash (FA) served as the adsorbent material, and its modified form (AFA) was developed via response surface optimization. The study involved an analysis of the structure and chemical composition of the fly ash before and after modification, both pre- and post-modification, through the use of scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR) analyses. These analyses were aimed at exploring the adsorption mechanism of ciprofloxacin (CIP) in the presence of copper ion (Cu 2+ ) in livestock and poultry wastewater. The study indicates that the optimal modification parameters for AFA include an alkali-to-ash ratio of 1.5, a calcination temperature of 400 °C, and a 3-hour calcination period. At pH 6, AFA exhibited a markedly superior adsorption capacity for CIP in comparison to FA, with AFA achieving 19.32 mg/g and FA only 9.61 mg/g. The adsorption process conforms to the quasi-second-order kinetic model and Langmuir isothermal model.The adsorption capacity for CIP increases at low concentrations, specifically when Cu 2+ levels are below 100 mg/L. Nevertheless, elevated CIP concentrations impede the adsorption process. The adsorption of AFA for CIP is observed to decrease with rising temperature, in contrast to the adsorption of Cu 2+ , which increases as the temperature rises. The adsorption mechanism of AFA is primarily comprised of pore filling, ion exchange, electrostatic interaction, π bond coordination, complexation, and other similar processes. • Optimized preparation of modified fly ash with high adsorption performance. • The adsorption effect of fly ash was evaluated by SEM, XRD and FT-IR. • The adsorption of CIP by AFA at varying Cu 2+ concentrations are investigated. • Adsorption involves pore filling, ion exchange, complexation, etc. • Help solve complex pollution problems in livestock and poultry wastewater.