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A highly constrained <i>cis</i>-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation

Nereida Hidalgo, Felipe de la Cruz‐Martínez, M. Trinidad Martín, M. Carmen Nicasio, Jesús Campos

2022Chemical Communications11 citationsDOIOpen Access PDF

Abstract

We have trapped a unique square planar cis -dihydride structure, of relevance for many catalytic transformations, through a bimetallic FLP-based approach.

Topics & Concepts

PlatinumBimetallic stripTerphenylSteric effectsChemistryPhotochemistryCrystallographyCatalysisStereochemistryOrganic chemistryOrganoboron and organosilicon chemistrySynthesis and characterization of novel inorganic/organometallic compoundsCoordination Chemistry and Organometallics
A highly constrained <i>cis</i>-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation | Litcius