Where do the Fluorine Atoms Go in Inorganic‐Oxide Fluorinations? A Fluorooxoborate Illustration under Terahertz Light
Chunjie Shen, Feng Zhang, Tetsuo Sasaki, Chaolu Eerdun, Michitoshi Hayashi, Houng‐Wei Wang, Keisuke Tominaga, Miriding Mutailipu, Shilie Pan
Abstract
Abstract The substitution of fluorine atoms for oxygen atoms/hydroxyl groups has emerged as a promising strategy to enhance the physical and chemical properties of oxides/hydroxides in fluorine chemistry. However, distinguishing fluorine from oxygen/hydroxyl in the reaction products poses a significant challenge in existing characterization methods. In this study, we illustrate that terahertz (THz) spectroscopy provides a powerful tool for addressing this challenge. To this end, we investigated two fluorination reactions of boric acid, utilizing MHF 2 (M=Na, C(NH 2 ) 3 ) as fluorine reagents. Through an interplay between THz spectroscopy and solid‐state density functional theory, we have conclusively demonstrated that fluorine atoms exclusively bind with the sp 3 ‐boron but not with the sp 2 ‐boron in the reaction products of Na[B(OH) 3 ][B 3 O 3 F 2 (OH) 2 ] (NaBOFH) and [C(NH 2 ) 3 ] 2 B 3 O 3 F 4 OH (GBF2). Based on this evidence, we have proposed a reaction pathway for the fluorinations under investigation, a process previously hindered due to structural ambiguity. This work represents a step forward in gaining a deeper understanding of the precise structures and reaction mechanisms involved in the fluorination of oxides/hydroxides, illuminated by the insights provided by THz spectroscopy.