Polymolybdate-guided assembly of a thiacalix[4]arene-protected Ag nanocluster for electrocatalytic CO<sub>2</sub>reduction
Shang-Qian Li, Lin-Fang Dai, Yi-Qi Tian, Xiao‐Yi Yi, Jun Yan, Chao Liu
Abstract
A polymolybdate-templated {Ag49Mo16} cluster stabilized by six thiacalix[4]arene ligands has been synthesized by a one-pot solvothermal reaction, which displays superior CO evolution activity for the electrocatalytic CO 2 reduction.
Topics & Concepts
PolyoxometalateCluster (spacecraft)ChemistryMoleculeCalixareneCombinatorial chemistryCrystallographyNanotechnologyMaterials scienceCatalysisOrganic chemistryProgramming languageComputer scienceNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in CatalysisPolyoxometalates: Synthesis and Applications