Bio-derived Schiff base vitrimer with outstanding flame retardancy, toughness, antibacterial, dielectric and recycling properties
Guofeng Ye, Cheng Wang, Qi Zhang, Pingan Song, Hao Wang, Siqi Huo, Zhitian Liu
Abstract
Thermosetting resins are widely used in high-tech applications for excellent mechanical robustness and chemical resistance. With increasing attention to the environmental and usage safety issues, it is necessary to develop bio-derived, recyclable, tough, and fire-retardant thermosetting resins. Herein, a high-performance, vanillin-based vitrimer (CIP 1.0 ) was prepared. The CIP 1.0 with 1.0 wt% phosphorus passes vertical burning (UL-94) V-0 rating with a limiting oxygen index (LOI) of 27.2%. The phosphorus-containing and Schiff base groups act synergistically in gas and condensed phases during combustion, endowing CIP 1.0 with outstanding fire retardancy. The CIP 1.0 shows excellent toughness with high elongation at break of 45.0% due to the π-π stacking of numerous rigid aromatic groups and appropriate cross-linking density. The highly symmetrical structure and low polarizability of CIP 1.0 result in a low dielectric constant. The CIP 1.0 exhibits superior antimicrobial properties. The CIP 1.0 can be reprocessed by hot-pressing at 140 °C for 10 min. The non-destructive, closed-loop recycling of carbon fibers in the carbon fiber-reinforced CIP 1.0 composite can be achieved under mild conditions due to the degradable Schiff base groups of CIP 1.0 . In this work, a bio-derived, tough, fire-retardant, low dielectric, and antimicrobial vitrimer is prepared to provide a rational strategy for the design of advanced environmentally friendly thermosetting resins.