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Thermal Performance and Shape Stability Evaluation of Boron Nitride and Expanded Graphite Synergy in Beeswax‐Based Composite Phase Change Material

Anas Islam, A.K. Pandey, Kosheela Devi Poo Palam, Yasir Ali Bhutto, R. Saidur

2025Energy Storage7 citationsDOIOpen Access PDF

Abstract

ABSTRACT Phase change materials (PCMs) are efficient thermal energy storage materials due to their high energy density and ability to maintain a constant temperature during phase transitions. Nonetheless, the low thermal conductivity and liquid phase leakage of PCMs constrain their efficient heat transfer and widespread adoption. The development of leakage‐free composite PCMs with high thermal conductivity remained a challenge. This work presents the first synergistic enhancement of thermal conductivity and shape stability of beeswax PCM with a dual‐scale filler system of h‐BN nanoparticles and EG microparticles that has not been reported previously in the literature. The composite containing 3 wt.% of h‐BN with 10 wt.% of EG exhibited no leakage at 80°C, with a 312% enhancement in thermal conductivity and a 68.5% decrease in light transmittance. Only a minor reduction of ~12% in latent heat was noted in comparison to the base PCM. Further, the composite exhibited comparable performance after 300 thermal cycles.

Topics & Concepts

Materials scienceThermal conductivityBoron nitrideComposite materialComposite numberPhase-change materialThermal stabilityThermal energy storageGraphiteThermal conductionHeat transferLatent heatThermalLeakage (economics)Thermal resistanceThermal energyPhase changeBoronPhase (matter)Heat transfer enhancementThermal effusivityThermal diffusivityConductivityWork (physics)NitrideNanoparticlePhase Change Materials ResearchAdvanced Battery Technologies ResearchAdvanced Battery Materials and Technologies