Advances in silylation and borylation of fluoroarenes and <i>gem</i>-difluoroalkenes <i>via</i> C–F bond cleavage
Juan Zhang, Shasha Geng, Feng Zhang
Abstract
-difluoroalkenes from 2000 to 2021, which might create some new ideas and will be helpful for further research in this field. These defluoroborylation and defluorosilylation strategies can be applied to synthesize silylated arenes, borylated arenes, silylated fluoroalkenes, and borylated fluoroalkenes, thus providing impressive advantages over traditional methods for the synthesis of organoboron and organosilane compounds in terms of divergent structures.
Topics & Concepts
BorylationSilylationCleavage (geology)ChemistryBond cleavageMedicinal chemistryStereochemistryPhotochemistryOrganic chemistryCatalysisMaterials scienceArylFracture (geology)Composite materialAlkylFluorine in Organic ChemistryCarbon dioxide utilization in catalysisOrganoboron and organosilicon chemistry