Ligand design of zero-field splitting in trigonal prismatic Ni(<scp>ii</scp>) cage complexes
Anthony J. Campanella, Tyler M. Ozvat, Joseph M. Zadrozny
Abstract
. These results demonstrate a remarkable flexibility of the zero-field splitting and electronic structure in nickelous cages and give a clear toolkit for modifying zero-field splitting in highly stable ligand shells.
Topics & Concepts
Zero field splittingLigand (biochemistry)CrystallographyIonChemistryElectron paramagnetic resonanceZero (linguistics)Field (mathematics)Ligand field theoryCageNanotechnologyMaterials sciencePhysicsElectronNuclear magnetic resonanceQuantum mechanicsReceptorMathematicsPure mathematicsLinguisticsOrganic chemistrySpin polarizationPhilosophyBiochemistryCombinatoricsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesPorphyrin and Phthalocyanine Chemistry