Synthesis and characterization of a bimetallic americium(<scp>iii</scp>) pyrithionate coordination complex
Zachary K. Huffman, Joseph M. Sperling, Cory J. Windorff, Brian N. Long, Lucas Cordova, Harry Ramanantoanina, Cristian Celis‐Barros, Thomas E. Albrecht‐Schmitt
Abstract
O shows significant splitting in the fingerprint excitations. This is attributed to a unique ligand-field environment, where the Am-mpo bonds possess different bonding compared to the Nd(III) analog because of increasing covalent interactions.
Topics & Concepts
ChemistryBimetallic stripIsostructuralLanthanideCovalent bondLigand (biochemistry)Aqueous solutionCrystallographyAbsorption spectroscopyMyeloperoxidaseBlock (permutation group theory)StereochemistryIonPhysical chemistryMetalCrystal structureOrganic chemistryReceptorBiochemistryInflammationMedicineQuantum mechanicsMathematicsGeometryInternal medicinePhysicsLanthanide and Transition Metal ComplexesMagnetism in coordination complexesMetal-Organic Frameworks: Synthesis and Applications