Visible light-induced hydrogen atom transfer trifluoromethylthiolation of aldehydes with bismuth catalyst
Jun Dong, Zhuang Tang, Luqian Zou, Yongyun Zhou, Jingchao Chen
Abstract
By using a combination of BiCl 3 and TBACl as a ligand-to-metal charge transfer (LMCT) photocatalyst, hydrogen atom transfer trifluoromethylthiolation of aldehydes was achieved under visible light irradiation.
Topics & Concepts
BismuthCatalysisHydrogen atomPhotochemistryChemistryHydrogenAtom (system on chip)Visible spectrumMaterials scienceOrganic chemistryOptoelectronicsComputer scienceAlkylEmbedded systemFluorine in Organic ChemistryRadical Photochemical ReactionsSulfur-Based Synthesis Techniques