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Photoactive perylenediimide metal–organic framework for boosting iodoperfluoroalkylation of alkenes and oxidative coupling of amines

Zhengfen Liu, Chao Li, Jian Chen, Xiaobo Li, Fumang Luo, Feixiang Cheng, Jian‐Jun Liu

2021Inorganic Chemistry Frontiers42 citationsDOI

Abstract

A novel photoactive MOF was prepared based on an electron-deficient perylenediimide derivative, which exhibits excellent photocatalytic activities towards the iodoperfluoroalkylation of alkenes and the oxidation of amines to imines.

Topics & Concepts

Oxidative coupling of methanePhotocatalysisPhotochemistryMetalOxidative phosphorylationDerivative (finance)ChemistryMaterials scienceOrganic chemistryCatalysisBusinessBiochemistryFinanceMetal-Organic Frameworks: Synthesis and ApplicationsFluorine in Organic ChemistryCovalent Organic Framework Applications