Deaminative radical reactions <i>via</i> relayed proton-coupled electron transfer
Qianqian Shi, Kuohong Chen, Limin Guo, Lili Han, Donghui Wei, Yu Lan
Abstract
The detailed mechanism of these kinds of N-heterocyclic carbene-catalyzed deaminative radical reactions has been explored in theory for the first time.
Topics & Concepts
ChemistryCarbeneProtonComputational chemistryElectron transferRadical ionElectronPhotochemistryCombinatorial chemistryCatalysisOrganic chemistryIonNuclear physicsPhysicsCatalytic C–H Functionalization MethodsN-Heterocyclic Carbenes in Organic and Inorganic ChemistryRadical Photochemical Reactions