High entropy 2D metals sulfides: Fast synthesis, exfoliation and electrochemical activity in overall water splitting at alkaline pH
Vladislav Buravets, Elena Miliutina, Vasilii Burtsev, Kamil Severa, Vera Shilenko, Jana Rosenkranzová, Philipp Hönicke, Tomáš Hrbek, Václav Švorčı́k, Oleksiy Lyutakov
Abstract
Novel simple and efficient method for synthesis of 2D high entropy sulfides of iron group metals is described. The method utilizes inorganic salts as precursors and CS 2 as a sulfurizing agent, which makes it possible to achieve high entropy composition through combination of freezing of the precursor solution, subsequent freeze-drying step, sulfurization, and exfoliation in liquid nitrogen. The created material was investigated as a catalyst for electrochemical water splitting at different pH. Measured overpotentials at 10 and 100 mA*cm −2 current densities for hydrogen evolution reaction (HER) were found to be 49 and 315 mV respectively, while for oxygen evolution reaction (OER) the overpotentials required for reaching 10 and 100 mA*cm −2 current densities were 370 and 591 mV respectively, both in 1 M KOH solution. The Tafel slopes for HER were found to be 235, 105, and 111 mV/dec in basic, neutral, and acidic conditions, respectively, while only 63 mV/dec for OER in basic conditions. The calculated values of the turnover frequency were 0.62 s −1 for HER and 0.10 s −1 for OER. We also confirmed the key role of high entropy in the catalytic activity of the material by excluding individual elements from the composition of the HES.