Lewis acid-triggered photocatalytic hydrogen peroxide production in an aluminum-based metal–organic framework
Yoshifumi Kondo, Kenta Hino, Yasutaka Kuwahara, Kohsuke Mori, Hisayoshi Kobayashi, Hiromi Yamashita
Abstract
Al-based MIL-101-NH 2 , which was previously regarded as having silent photo-features, exhibits photocatalytic H 2 O 2 production via O 2 reduction accompanied by efficient suppression of undesired H 2 O 2 decomposition.
Topics & Concepts
Hydrogen peroxidePhotocatalysisDecompositionLewis acids and basesChemistryPhotochemistryAluminiumVisible spectrumMetalElectron transferCatalysisMetal-organic frameworkInorganic chemistryMaterials scienceOrganic chemistryAdsorptionOptoelectronicsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and Applications