Guest induced reversible on–off switching of elastic frustration in a 3D spin crossover coordination polymer with room temperature hysteretic behaviour
Lucı́a Piñeiro-López, Francisco Javier Valverde‐Muñoz, Elżbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells‐Gil, Iván da Silva, Carlos Martí‐Gastaldo, Éric Collet, José Antonio Real
Abstract
) and the elastic frustration, and reversibly switches back to the original four-step behaviour upon guest re-adsorption. Both uncommon relevant SCO events meeting in the same material represent a rare opportunity to compare them in the frame of antiferro- and ferro-elastic transitions.
Topics & Concepts
Spin crossoverFrustrationMetastabilityCrystallographySpin statesCondensed matter physicsSpin transitionCoordination polymerPopulationChemistryMaterials scienceCrystal structurePhysicsDemographySociologyOrganic chemistryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research