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Green synthesis of copper oxide nanoparticles using neem leaf extract ( <i>Azadirachta indica</i> ) for energy storage applications

Imosobomeh L. Ikhioya, Agnes C. Nkele, Faith U. Ochai-Ejeh

2023Materials Research Innovations14 citationsDOI

Abstract

The green synthesis method was utilised in synthesising copper oxide nanoparticles from Azadirachta indica using copper sulphate as the precursor at different molarities. The nanoparticles were investigated using X-ray diffractometry (XRD), Scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), UV-Vis spectrophotometry, and potentiometry to understand their respective structural, morphological, elemental, optical, and electrochemical properties. Crystalline diffraction peaks with nanospheres distributed through the surface. The elemental compositions of the as-deposited elements were confirmed from the EDX spectra. High optical absorbance and energy band gap values ranging from 1.75 eV to 2.72 eV at increasing molarities were obtained. Good cyclic voltammograms measured at a scan rate of 20 mV/s yielded a maximum specific capacitance of 148 F/g. The synthesised nanoparticles would find useful applications in supercapacitors and electrochemical devices.

Topics & Concepts

Materials scienceSupercapacitorAbsorbanceCapacitanceAzadirachtaNanoparticleCopperScanning electron microscopeCopper oxideBand gapElectrochemistryAnalytical Chemistry (journal)Cyclic voltammetryChemical engineeringOxideNuclear chemistryNanotechnologyOptoelectronicsMetallurgyElectrodeComposite materialChemistryOrganic chemistryPhysical chemistryChromatographyBiologyHorticultureEngineeringCopper-based nanomaterials and applicationsNanoparticles: synthesis and applicationsZnO doping and properties