Effect of magnetite nanoparticles on the structure, thermal and magnetic properties of the high-density polyethylene
F. V. Hajiyeva, H. A. Shirinova, M. A. Jafarov, Luca Di Palma, Maria Paola Bracciale, Irene Bavasso, Stefano Bellucci, S. Alleg
Abstract
High-density polyethylene (HDPE) nanocomposites with Fe 3 O 4 nanoparticles were synthesized and analyzed for structural, thermal, and magnetic properties. X-ray diffraction showed an increase in Fe 3 O 4 crystallite size from 5.14 nm to 12.01 nm, while the HDPE crystalline size decreased from 14 nm to 4.88 nm for HDPE + 3% Fe 3 O 4 and HDPE + 40% Fe 3 O 4 , respectively. Thermogravimetric analysis showed improved thermal stability, with the onset temperature increasing from 243.78°C (HDPE) to 395.13°C (HDPE + 40% Fe 3 O 4 ). Differential scanning calorimetry indicated a crystallinity rise from 44.45% to 51.95% (HDPE + 40% Fe 3 O 4 ), while melting and crystallization temperatures remained near 104°C and 94°C, respectively. Magnetic characterization revealed that the saturation magnetization increased from 49.61 × 10 −3 emu for HDPE +1% Fe 3 O 4 to 52.98 × 10 −3 emu for HDPE +10% Fe 3 O 4 , while the coercivity decreased from 17.76 G for HDPE + 5% Fe 3 O 4 to 6.30 G for HDPE + 1% Fe 3 O 4 . This reduction in coercivity suggests a transition from a single-domain to a multi-domain state, likely due to nanoparticle aggregation at higher concentrations. These results demonstrate the potential of HDPE/Fe 3 O 4 nanocomposites for thermally stable and magnetically tunable applications.