Core–Shell Co<sub>2</sub>VO<sub>4</sub>/Carbon Composite Anode for Highly Stable and Fast-Charging Sodium-Ion Batteries
Cong Wang, Zhenyu Wang, Zhenyu Wang, Decheng Zhao, Jinghui Ren, Shupei Liu, Hao Tang, Peng Xu, Fei Gao, Xiang-an Yue, Han Yang, Chunming Niu, Weishen Chu, Di Wang, Xiang Liu, Zhoulu Wang, Zhoulu Wang, Yutong Wu, Yi Zhang
Abstract
Sodium-ion batteries (SIBs) are promising candidates for large-scale energy storage systems due to the abundance and wide distribution of sodium resources. Various solutions have been successfully applied to revolve the large-ion-size-induced battery issues at the mid-to-low current density range. However, the fast-charging properties of SIBs are still in high demand to accommodate the increasing energy needs at large to grid scales. Herein, a core–shell Co2VO4/carbon composite anode is designed to tackle the fast-charging problem of SIBs. The synergetic effect from the stable spinel structure of Co2VO4, the size of the nanospheres, and the carbon shell provide enhanced Na+ ion diffusion and electron transfer rates and outstanding electrochemical performance. With an ultrahigh current density of 5 A g–1, the Co2VO4@C anode achieved a capacity of 135.1 mAh g–1 and a >98% capacity retention after 2000 cycles through a pseudocapacitive dominant process. This study provides insights for SIB fast-charging material design and other battery systems such as lithium-ion batteries.