Polarization‐Dependent Sum‐Frequency‐Generation Spectroscopy for In Situ Tracking of Nanoparticle Morphology
Verena Pramhaas, Holger Unterhalt, Hans‐Joachim Freund, Günther Rupprechter
Abstract
The surface structure of oxide-supported metal nanoparticles can be determined via characteristic vibrations of adsorbed probe molecules such as CO. Usually, spectroscopic studies focus on peak position and intensity, which are related to binding geometries and number of adsorption sites, respectively. Employing two differently prepared model catalysts, it is demonstrated that polarization-dependent sum-frequency-generation (SFG) spectroscopy reveals the average surface structure and shape of the nanoparticles. SFG results for different particle sizes and morphologies are compared to direct real-space structure analysis by TEM and STM. The described feature of SFG could be used to monitor particle restructuring in situ and may be a valuable tool for operando catalysis.