Extraction and Depolymerization of Lignin from Pine Sawdust and Pistachio Shells
Balawanthrao Jadhav, Ranen Roy, Md Sajjadur Rahman, Douglas E. Raynie
Abstract
Lignocellulosic biomass is a renewable resource that contains three major constituents: cellulose, hemicellulose, and lignin. Lignin is a potential source of aromatic phenols. The extraction and subsequent depolymerization of lignin was studied using pine sawdust and pistachio shells. Lignin extraction used 70:30 methyl isobutyl ketone:ethanol followed by 0.1M H2SO4. The extraction yield of lignin was 15.78 ± 3.38% from pistachio shells and 18.86 ± 1.52% from pine sawdust. The extracted lignin was characterized using Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and 1H-NMR spectroscopy. The extracted lignin was depolymerized using subcritical water and a Ni-Graphene catalyst at 240 °C for 10 min. The depolymerization products were identified as phenolic monomers, such as phenol, guaiacol, vanillin, syringol, guaiacylpropane, syringaldehyde, coniferaldehyde, synapyl alcohol, and synapyl aldehyde, using GC-MS.