Breaking the upper bound of siloxane uptake: metal–organic frameworks as an adsorbent platform
Ezgi Gulcay-Ozcan, Paul Iacomi, Youngsang Ko, Jong‐San Chang, Guillaume Rioland, Sabine Devautour‐Vinot, Guillaume Maurin
Abstract
High throughput computational screening in tandem with synthesis and adsorption testing revealed hydrophobic Zr-MOF PCN-777 as an optimal siloxane adsorbent with record gravimetric uptake (1.8 g g −1 ), reversible and fast adsorption, good cyclability and easy regeneration.
Topics & Concepts
SiloxaneAdsorptionGravimetric analysisTandemMetal-organic frameworkChemical engineeringChemistryMaterials scienceOrganic chemistryPolymerComposite materialEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsGas Sensing Nanomaterials and Sensors