Decade Advances of NaN <sub>3</sub> in Three‐component Reactions
Zhan‐Yong Wang, Jiarong Li, Nan Wang, Hong Liu, Kai‐Kai Wang
Abstract
Abstract Decade advances of sodium azide (2011–2022) have been summarized via mechanisms and target products. Sodium azide is commonly used as a nucleophile (N 3 − ) or radical source (⋅N 3 ) in three‐component reactions. It's reactions with alkenes, alkynes, R−X (X=F, Cl, Br, I, OTs, B(OH) 2 , BF 3 K, I + ArO − Tf, N 2 + O − SO 3 ‐SiO 2 ) and other electrophiles will be discussed.
Topics & Concepts
ChemistrySodium azideElectrophileNucleophileComponent (thermodynamics)SodiumAzideMedicinal chemistryOrganic chemistryCatalysisPhysicsThermodynamicsClick Chemistry and ApplicationsChemical Synthesis and AnalysisSynthesis and Biological Evaluation