Ti<sub>4</sub>(embonate)<sub>6</sub> Cage-Ligand Strategy on the Construction of Metal–Organic Frameworks with High Stability and Gas Sorption Properties
Yan‐Ping He, Guang‐Hui Chen, Lv‐Bing Yuan, Lei Zhang, Jian Zhang
Abstract
Herein we report an efficient strategy to construct cage-based metal–organic frameworks (MOFs) via the assembly of Ti4L6 (L = embonate) cages and N-contained ligands with Mn2+ and Zn2+ ions, respectively, and two Ti4L6-cage-based MOFs (PTC-219 and PTC-220) with high stability and gas sorption properties have been generated through two-step reactions, respectively.
Topics & Concepts
ChemistryCageSorptionMetal-organic frameworkLigand (biochemistry)MetalIonMetal ions in aqueous solutionChemical stabilityInorganic chemistryChemical engineeringPolymer chemistryOrganic chemistryAdsorptionMathematicsReceptorCombinatoricsEngineeringBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsNanoplatforms for cancer theranosticsSupramolecular Chemistry and Complexes