Anchoring Carbon-Coated CoSe Nanoparticles on Hollow Carbon Nanocapsules for Efficient Potassium Storage
Zhuangzhuang Zhang, Beining Zhang, Jingyi Xu, Min Zhang, Liping Duan, Jian Shen, Xiaosi Zhou
Abstract
Research on potassium-ion batteries (PIBs) has recently been reemphasized because of the irreplaceable advantages of abundant resource, cheap price, and comparable standard redox potential to lithium, displaying great potential for large-scale energy conversion. Nevertheless, the development of PIBs is tremendously hindered due to the shortage of matching electrode materials that can reversibly uptake/release larger K+ during discharging and charging. Herein, we report the fabrication of double-layer carbon-coated CoSe hollow nanocapsules (denoted as CoSe@C/HCPs) using a flexible template-assisted strategy. The as-prepared CoSe@C/HCPs exhibit enhanced electrochemical performance as an anode material for PIBs. In particular, they can deliver a high reversible capacity of 461 mAh g–1 at 100 mA g–1, an extraordinary rate capability of 278 mAh g–1 at 3 A g–1, and decent cycling stability with 182 mAh g–1 retained at 3 A g–1 after 300 cycles. More importantly, a full PIB cell (P2-type K0.6CoO2 used as the cathode material) also demonstrates an improved electrochemical performance (168 mAh g–1 at 100 mA g–1 after 100 cycles). These current studies have made a vanguard attempt to synthesize selenium-based anodes with sophisticated hierarchical architectures for PIBs, which could provide extensive impetus for the evolution of advanced PIBs.