Photoluminescence Quenching in Recyclable Water-Soluble Zn-Based Metal–Organic Framework Nanoflakes for Dichromate Sensing
Yi Zhang, Yuhang Liu, Feng Huo, Baowen Zhang, Wenzhen Su, Xiupei Yang
Abstract
Nanoflakes are materials with high dispersion, a large specific surface area, and a high number of active sites that can provide a good platform for various fluorescence sensors and are very popular among researchers. In this study, a nanoflake-like zinc metal–organic framework (Zn-MOF) was successfully synthesized from the organic ligand 1,2,4,5-tetra(1H-imidazol-1-yl)benzene and zinc nitrate. The synthesized Zn-MOF nanoflakes are extremely soluble in water and exhibit high fluorescence stability. Since Cr2O72– can significantly quench the fluorescence of Zn-MOF aqueous solution, a rapid detection method for Cr2O72– content in water was constructed with a linear range and linear correlation of 0.3–20 μM and 0.992, respectively. The fluorescence quenching constant of the Zn-MOF is KSV = 2.003 × 104 M–1, and the detection limit for Cr2O72– is as low as 0.09 μM. Through the study of fluorescence lifetime and UV absorption, it is proven that the mechanism of Cr2O72– quenching the fluorescence of the Zn-MOF is the inner filter effect. In addition, even after being applied five times, the Zn-MOF still maintained good detection performance for Cr2O72–. The proposed method was successfully applied to the determination of real water samples, confirming that it can be used as an alternative method for the detection of Cr2O72– in environmental samples.