Introduction of electron-deficient unit in resorcinol-formaldehyde resin to construct donor–acceptor conjugated polymer for enhancing photocatalytic H<sub>2</sub>O<sub>2</sub> production
Xinyue Li, Qiuang Zheng, Xiaoran Wang, Qiuyu Zheng, Yi Zhang, Yanqing Cong, Shi‐Wen Lv
Abstract
Intramolecular donor–acceptor conjugated polymer was constructed in resorcinol-formaldehyde resin by embedding benzothiadiazole, which can reduce the Gibbs free energy for two-electron oxygen reduction and improve photocatalytic H 2 O 2 evolution.
Topics & Concepts
Conjugated systemFormaldehydePhotocatalysisResorcinolPolymerElectron acceptorAcceptorElectron donorMaterials sciencePhotochemistryChemical engineeringChemistryNuclear chemistryPolymer chemistryCatalysisOrganic chemistryPhysicsEngineeringCondensed matter physicsAdvanced Photocatalysis TechniquesCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and Applications