Dynamic activation catalysts for CO2 hydrogenation
Zhewei Zhang, Jun Yao, Chenyang Shen, Fengfeng Li, Changshun Deng, Taotao Zhao, Xuefeng Guo, Yan Zhu, Xiangke Guo, Nianhua Xue, Luming Peng, Weiping Ding
Abstract
Abstract In typical heterogeneous catalytic reactions, catalysts, whether fixed or flowing, maintained their bulk and surface structures as stable as possible. We report here dynamic activation catalysts having continuously generate highly active sites in working, which enables a usually low active Cu/Al 2 O 3 catalyst for CO 2 hydrogenation, showing extraordinary catalytic performances. Using reaction streams in unusually high linear speed to blow and carry the Cu/Al 2 O 3 particulates to collide cyclically with a rigid target, the CO 2 conversion rate is more than three times enhanced at methanol selectivity promoted to 95% from less than 40% and the methanol space-time-yield is six times increased. By experimental and theoretical investigation, the dynamic activation of Cu/Al 2 O 3 is defined as a discrete condensed state with a distorted and elongated lattice, reduced coordination, and abnormal catalytic properties. We envision that continuous research on the dynamical activation catalysts will advance novel methods for promoting catalytic performance and discovering new catalytic reactions.