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Ionic conductivity of the Ag<sub>8</sub>GeSe<sub>6</sub> compound

R. M. Sardarly, Garay M. Ashirov, Leyla F. Mashadiyeva, N. A. Aliyeva, F. T. Salmanov, R. Sh. Agayeva, R. A. Mamedov, М. Б. Бабанлы

2022Modern Physics Letters B26 citationsDOI

Abstract

The temperature dependences of the conductivity and permittivity of the Ag 8 GeSe 6 compound have been studied in direct and alternating electric fields. This phenomenon is associated with the process of charge accumulation at the boundary of the sample with ionic conductivity and the blocking electrode, and the formation of a double electric layer. The observed dielectric relaxation is associated with the transition of the crystal to the superionic state. It has been established that hopping conduction with a variable hopping length over localized states near the Fermi level takes place in an Ag 8 GeSe 6 crystal.

Topics & Concepts

Materials scienceCondensed matter physicsIonic conductivityPermittivityDielectricRelaxation (psychology)Ionic bondingThermal conductionConductivityElectrical resistivity and conductivityVariable-range hoppingElectric fieldCrystal (programming language)ElectrodeIonElectrolyteChemistryPhysical chemistryPhysicsOptoelectronicsSocial psychologyProgramming languageComputer scienceQuantum mechanicsComposite materialPsychologyOrganic chemistryPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallographyChalcogenide Semiconductor Thin Films
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