Litcius/Paper detail

On the existence of low-valent magnesium–calcium complexes

Jonathan Mai, Bastian Rösch, Neha Patel, Jens Langer, Sjoerd Harder

2023Chemical Science34 citationsDOIOpen Access PDF

Abstract

While low-valent β-diketiminate complexes with a Mg–Mg bond are well-established, similar Ca–Ca bound complexes were hitherto too reactive to be isolated. Herein we discuss the possible formation of low-valent heterobimetallic Mg–Ca complexes.

Topics & Concepts

MagnesiumCalciumChemistryLow calciumInorganic chemistryCrystallographyOrganic chemistryOrganometallic Complex Synthesis and CatalysisSynthesis and characterization of novel inorganic/organometallic compoundsCoordination Chemistry and Organometallics