Snapshots of sequential polyphosphide rearrangement upon metallatetrylene addition
Xiaofei Sun, Alexander Hinz, Stephan Schulz, Lisa Zimmermann, Manfred Scheer, Peter W. Roesky
Abstract
] was also investigated. All the isolated complexes represent rare examples of mixed group 13/14 iron polypnictogenides, which could only be synthesized by taking advantage of the cooperativity of the gallatetrylenes featuring low-valent Si(ii) or Ge(ii) and Lewis acidic Ga(iii) units/entities.
Topics & Concepts
Surface modificationChemistryMedicinal chemistryStereochemistryPhysical chemistrySynthesis and characterization of novel inorganic/organometallic compoundsOrganoboron and organosilicon chemistryOrganometallic Complex Synthesis and Catalysis