Pultruded carbon fibre reinforced polymer strips produced with a novel bio-based thermoset polyester for structural strengthening
Mateus Hofmann, Marina Machado, Abu T. Shahid, Filipe Dourado, Mário Garrido, João C. Bordado, João R. Correia
Abstract
This paper presents the development and industrial manufacturing of a pultruded high-performance carbon fibre (CF) reinforced polymer (CFRP) composite strip using a bio-based unsaturated polyester (UP) resin containing more than 50% of its weight derived from renewable raw materials. The bio-based CF/UP strengthening strip, comprising unidirectional CF strands, was successfully produced and its mechanical and thermomechanical behaviours were assessed, and compared to an equivalent carbon fibre reinforced epoxy-vinyl ester (CF/VE) strip produced with conventional petroleum-based high-performance epoxy-vinyl ester resin and the same fibre architecture. The bio-based CF/UP composite strip presented 2095 MPa, 167 GPa, and 1.4% of tensile strength, modulus of elasticity, and strain at failure, respectively. These figures met or exceeded the mechanical properties of its equivalent conventional CF/VE counterpart tested under the same conditions. Furthermore, the bio-based CF/UP composite strip presented a glass transition temperature of 78 °C (defined from the onset of the storage modulus decay), enabling a maximum service temperature of ∼60 °C, which will not likely be exceeded in most climates, highlighting its potential for structural strengthening applications, and offering a key advantage in terms of sustainability.