Linear and macrocyclic oligo(<i>p</i>-phenylene iminoboranes) with ferrocenyl side groups – observation of selective, non-templated macrocyclization
Johannes S. Schneider, Ivo Krummenacher, Holger Braunschweig, Holger Helten
Abstract
-phenylene vinylenes), featuring pendent ferrocene groups have been prepared. Stoichiometric reaction of a bis-silylamine with a bisborane led to selective formation of an unprecedented macrocycle, without the use of a template.
Topics & Concepts
PhenyleneFerroceneChemistryStoichiometryPolymer chemistryOrganic chemistryPolymerElectrochemistryElectrodePhysical chemistryOrganoboron and organosilicon chemistryBoron Compounds in ChemistrySynthesis and characterization of novel inorganic/organometallic compounds